Karakteristik Transfer Muatan pada DSSC dengan Fotoanoda Triple Layer Ag-TiO2

Titik Istirohah, Shahan Shah, Nur Amirah Mat Nor, Thathit Suprayogi, Markus Diantoro, Arif Hidayat, Ahmad Taufiq, Zainul Arifin Imam Supardi, Abdul Kariem Arof

Abstract


Dye Sensitized Solar Cell (DSSC) merupakan salah satu bagian dari energi terbarukan yang memiliki potensi besar dengan memanfaatkan energi dari sinar matahari menjadi energi listrik dengan bantuan sensitizer sebagai agen penyerap cahaya. Kemampuan konversi DSSC ditunjukkan oleh nilai Jsc (12,70 mA/cm2), Voc (0,585 V), FF (0,476), dan η (3,54%) yang diperoleh dari pengujian solar simulator. Selain parameter tersebut, karakteristik DSSC dapat juga ditunjukkan dari nilai ttr (0,010 s), trec (0,080 s), ηcc (0,874), D (0,192) dan  LD  (0,124 mm) melalui IMPS (Intensity Modulated Photocurrent Spectroscopy) dan IMVS (Intensity Modulated Photovoltage Spectroscopy). Pada artikel ini juga dilaporkan Impedansi antar lapisan DSSC melalui analisis EIS (Electrochemical Impedance Spectroscopy).

 

DOI: http://dx.doi.org/10.17977/um024v4i12019p023


Keywords


DSSC, transport muatan, triple layer Ag-TiO2, IMPS-IMVS, EIS.

References


J. N. Clifford, E. Martı, and E. Palomares, “Sensitizer Molecular Structure-Device Efficiency Relationship in Dye Sensitized Solar Cells”, Chem. Soc. Rev., vol. 40, no. 3, pp. 1635–1646, 2011.

Y. Ooyama and Y. Harima, “Photophysical and Electrochemical Properties, and Molecular Structures of Organic Dyes for Dye-Sensitized Solar Cells”, Chem. Phys. Chem., vol. 13, no. 18, pp. 4032–4080, 2012.

M. H. Buraidah et al., “High Efficient Dye Sensitized Solar Cells Using Phthaloylchitosan Based Gel Polymer Electrolytes Electrochimica Acta High Efficient Dye Sensitized Solar Cells Using Phthaloylchitosan Based Gel Polymer Electrolytes,” Electrochim. Acta, vol. 245, no. June, pp. 846–853, 2017.

O. Adedokun, K. Titilope, and A. O. Awodugba, “Review on Natural Dye-Sensitized Solar Cells (DSSCs),” Int. J. Eng. Technol. IJET, vol. 2, no. 2, p. 34, 2016.

J. Wu et al., “Counter Electrodes in Dye-Sensitized Solar Cells”, Chem. Soc. Rev., vol. 46, no. 19, pp. 5975–6023, 2017.

J. Gong et al., “Review on Dye-Sensitized Solar Cells (DSSCs): Advanced Techniques and Research Trends,” Renew. Sustain. Energy Rev., vol. 68, pp. 234–246, 2017.

Q. Liu et al. "Improved Photovoltaic Performance of Dye Sensitized Solar Cells (DSSCs) by Zn+ Mg Co-Doped TiO2 Electrode", Electrochim. Acta, vol 95, pp. 48–53, 2013.

K. Ishibashi, Y. Kimur, and M. Niwano, “An Extensive Valid and Stable Method for Derivation of All Parameters of A Solar Cell from A Single Current-Voltage Characteristic”, J. Applied Phy., vol. 103, no. 9, p. 094507, 2008.

M. Diantoro et al., “Shockley’s Equation Fit Analyses for Solar Cell Parameters from I-V Curves”, Int. J. of Photoenergy, vol. 2018, pp. 1–7, 2018.

M. Ye et al., “Electrochemical Methods for The Characterization and Interfacial Study of Dye-Sensitized Solar Cell”, Sci. Bull., vol. 60, no. 9, pp. 850–863, 2015.

P. Nbelayim et al., “Systematic Characterization of The Effect of Ag@TiO2 Nanoparticles on The Performance of Plasmonic Dye Sensitized Solar Cells”, Sci. Rep., vol. 7, no. 1, pp. 1–12, 2017.

A. K. B. M. Arof and M. H. B. A. Buraidah, Plasmonic Effect in Photoelectrochemical Cells, London: Plasmonic Intech Open, pp. 223–241, 2018.

S. Shah et al., “Plasmonic Effects of Quantum Size Metal Nanoparticles on Dye Sensitized Solar Cell”, Opt. Mater. Express, vol. 7, no. 6, pp. 1–7, 2017.

Z. A. Garmaroudi and M. R. Mohammadi, “Plasmonic Effects of Infiltrated Silver Nanoparticles Inside TiO2 Film: Enhanced Photovoltaic Performance in DSSCs”, J. American Ceramic Soc., vol. 173, pp. 167–173, 2016.

N. C. Jeong, C. Prasittichai, and J. T. Hupp, “Photocurrent Enhancement by Surface Plasmon Resonance of Silver Nanoparticles in Highly Porous Dye-Sensitized Solar Cells”, Langmuir, vol. 27, no. 23, pp. 14609–14614, 2011.

J. Lungu, A. Georgescu, and A. Dumbrava, “Original Research Paper Enhancing The Efficiency of AZO-Based Dye Sensitized Solar Cells by Surface Treatments”, Sci. Study & Research. Chem. & Chem. Eng. Biotechnology, Food Ind., vol. 16, no. 1, pp. 69–74, 2015.

M. H. Buraidah et al., “Solar Module Using Dye Sensitized Solar Cells”, 20th Int. Conf. Transparent Opt. Networks, pp. 1–4, 2018.

H. Yu et al., “An efficient and Low-Cost TiO2 Compact Layer for Performance Improvement of Dye-Sensitized Solar Cells”, Electrochim. Acta, vol. 54, pp. 1319–1324, 2009.

A. K. Arof et al., “Utilization of Saffron (Crocus Sativus L.) as Sensitizer in Dye Sensitized Solar Cells ( DSSCs )”, Opt. Quantum Electron., vol 49, no. 1, p. 37, 2017.

T. M. W. J. Bandara et al., “Efficiency Enhancement in Dye Sensitized Solar Cells with A Novel PAN Based Gel Polymer Electrolyte with Ternary Iodides”, J. of Solid State Electrochemistry, vol. 19, no. 8, pp. 2353–2359, 2015.

A. K. Arof et al., “Polyacrylonitrile Gel Polymer Electrolyte Based Dye Sensitized Solar Cells for A Prototype Solar Panel,” Electrochim. Acta, vol. 251, pp. 223–234, 2017.

H. C. Hassan et al., “A High Efficiency Chlorophyll Sensitized Solar Cell with Quasi Solid PVA Based Electrolyte”, Int. J. of Photoenergy, vol. 2016, pp. 1–9, 2016.

T. Suprayogi, D. Maftuha, and M. Diantoro, “Pembuatan DSSC dengan Fotoanoda dari TiO2 dan β-Karoten Sebagai Sensitizer dan Analisis Kurva IV,” JPSE (Journal Phys. Sci. Eng.), vol. 2, no. 2, pp. 11–18, 2018.

M. A. Green, Solar Cells: Operating Principles, Technology, and System Applications, Englewoods Cliffs: Prentice-Hall Inc., 1982.

W. S. Chi et al., “Hybrid Electrolytes Prepared from Ionic Liquid-Grafted Alumina for High-Efficiency Quasi-Solid-State Dye-Sensitized Solar Cells”, Nanoscale, vol. 5, no. 12, pp. 5341–5348, 2013.

M. Libratore et al., “Using EIS for Diagnosis of Dye-Sensitized Solar Cells Performance”, J. of Appl. Electrochemistry, vol. 39, no. 11, pp. 2291–2295, 2009.

S. S. Sekhon et al., “Gel Electrolyte Based on UV-Cured Polyurethane for Dye-Sensitized Solar Cells”, Curr. Appl. Phys., vol. 11, no. 1, pp. S158–S162, 2010.




Copyright (c) 2020 Titik Istirohah, Shahan Shah, Nur Amirah Mat Nor, Thathit Suprayogi, Markus Diantoro, Arif Hidayat, Ahmad Taufiq, Zainul Arifin Imam Supardi, Abdul Kariem Arof

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This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License